Catalytic Nucleophilic Allylation Driven by the Water–Gas Shift Reaction
نویسندگان
چکیده
منابع مشابه
The Isomerization of Allylrhodium Intermediates in the Rhodium-Catalyzed Nucleophilic Allylation of Cyclic Imines**
Allylrhodium species generated from potassium allyltrifluoroborates can undergo isomerization by 1,4-rhodium(I) migration to give more complex isomers, which then react with cyclic imines to provide products with up to three new stereochemical elements. High enantioselectivities are obtained using chiral diene-rhodium complexes.
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ژورنال
عنوان ژورنال: The Journal of Organic Chemistry
سال: 2017
ISSN: 0022-3263,1520-6904
DOI: 10.1021/acs.joc.7b02658